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pH and Conductivity Analyser Fault Finding Guide

A one page guide to pH and conductivity analyser problems: electrode condition, reference faults, coating, grounding and temperature compensation.

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pH and Conductivity Analyser Fault Finding Guide PDF preview

A one page A4 guide to print for the workshop or keep on your phone in the field. The full content is also shown below.

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Before you start

  • Permit, isolation and control room informed.
  • Put the loop in manual or inhibit trips as authorised.
  • Use certified test equipment in hazardous areas.
  • Record as found readings before changing anything.

Quick checks

  • Slope and offset from last calibration?
  • Sensor clean and wet?
  • Temperature reading correct?
  • Analyser and lab agree?
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Symptoms, causes and fixes

SymptomLikely causesChecks and fixes
Low slopeAged or coated glass, old buffersClean; fresh buffers; replace if below limit
Large offsetReference poisoned or junction blockedClean junction; replace sensor
Slow responseCoating, dry glass, cold sampleClean and rehydrate; check temperature
DriftingReference problem, ground loop, flow effectsCheck solution ground; isolate; stable flow
Conductivity reads lowCoating, air in cell, wrong cell constantClean; remove air; calibrate
Temperature wrongFaulty temperature sensor or wiringCompare with thermometer; fix wiring
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Limits often used

  • pH slope about 90 to 105 % of Nernst.
  • pH offset within about ± 30 mV.
  • Conductivity standard within ± 2 % after calibration.

Related Tools, Procedures and Calculators

Frequently Asked Questions

Why is my pH slope low?

The glass is ageing or coated; clean, use fresh buffers, and replace if it stays low.

What causes pH drift?

Reference junction problems or ground loops.

Why calibrate with fresh buffers?

Old or contaminated buffers give wrong calibration values.

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